Most manufacturers guarantee the batteries for 8 years or so, so it shouldn't be a major concern tbh. My last car, a Cupra Formentor PHEV stated in the manual that if charged to 100% then the car should be driven as soon as possible i.e. not left stood for many hours/days whilst at 100% charge. Having said that, the guarantee remains, how could they prove how it's been charged etc.
I have read that the HV batteries get stressed if left at 100% or 0% for long periods. Many mobile phone/tablet manufacturers say the same and many have an option to only charge to 80% "to protect the battery". I've always charged my phone to 100% overnight, every night, and never had an issue.
My PHEV's, past & present, have sometimes been left for several days unused, so I do set the option to charge up to 80/90% and then top up to 100% a few hours before travelling, but that's just my preference (I do have a dedicated home charging point so it's much easier to control than the Ford Pass app). One big advantage though is that if its plugged in just before a journey, the car can be conditioned i.e. heated or cooled without using the car's power.